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[107730] Artykuł: Studies on Carbon Materials Produced from Salts with Anions Containing Carbon Atoms for Carbon Paste ElectrodeCzasopismo: Materials Tom: 14, Strony: 2480ISSN: 1996-1944 Opublikowano: 2021 Autorzy / Redaktorzy / Twórcy Grupa MNiSW: Publikacja w czasopismach wymienionych w wykazie ministra MNiSzW (część A) Punkty MNiSW: 140 DOI Keywords: combustion synthesis  salts with carbon in molecule  carbon materials  modified CPEs  |
In the presented work, the properties of carbon materials obtained in the reaction of sodium
bicarbonate (C-SB) and ammonium oxalate (C-AO) with magnesium by combustion synthesis were
investigated. For the materials obtained in this way, the influence of the type of precursor on their
properties was analyzed, including: Degree of crystallinity, porous structure, surface topography,
and electrochemical properties. It has been shown that the products obtained in magnesiothermic
process were found to contain largely the turbostratic carbon forming a petal-like graphene material.
Both materials were used as modifiers of carbon paste electrodes, which were then used to determine
the concentration of chlorophenol solutions by voltammetric method. It was shown that the peak
current determined from the registered differential pulse voltammograms was mainly influenced by
the volume of mesopores and the adsorption capacity of 4-chlorophenol for both obtained carbons.